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高山

发布时间:2015年06月05日  点击:[]

高山,男,教授、博士生导师。19667月出生。1985-1992年就读于黑龙江大学化学系,并先后获得理学学士和理学硕士学位,1992~1994年在哈尔滨工业大学化学系无机教研室任教,1998年获得福州大学化学系物理化学专业博士学位,随后在吉林大学无机合成与制备化学国家重点实验室 从事 博士后研究工作。1999年至今在黑龙江大学化学化工与材料学院任教目前涉及的主要研究领域为功能配位材料与纳米功能材料。作为主持人和主要参与人完成国家和省级基金等项目十余项,在研国家级和部级项目两项。近年来在国内外学术刊物J. Mater. Chem. A, Inorg. Chem., Cryst. Growth & Des., Organometallics, CystEngComm, Dalton Trans., Sensor Actuat B, Eur. J. Inorg. Chem., Inorg. Chem. Commun., Polyhedron等国际期刊上发表SCI论文百余篇,其中影响因子大于3.0的文章30余篇,总计被他人正面引用550余次。获得授权专利6项,通过黑龙江省科技厅鉴定成果一项(国际先进)。获省科技进步二等奖两项,省高校科技进步一等奖一项和二等奖两项。现为中国化学会会员和中国晶体学会员,并担任国际和国内某些知名SCI期刊的通讯评审人。

Emailshangao67@yahoo.com

学科专业:无机化学
研究领域:功能配位材料与纳米功能材料

主要研究方向:

1.      纳米孔金属有机晶态网络的设计合成与功能化。

2.      水溶性金属有机晶态网络的设计合成与发光性能。

3.      有机超分子晶态网络(药物共晶化合物)的组装与表征。

4.      多级结构微纳米氧化物的建构与敏感、储锂等性能研究。

代表性论文

1.      Jing Huang, Zhao-Peng Deng, Ying-Hui Xiao, Li-Hua Huo,* Shu-Nan Zhao,    Fa-Yuan Ge and Shan Gao*, Macrocyclic dinuclear, helical, layered and 3-D Ag(I) complexes constructed from AgX (X = NO3 and ClO4) and flexible bis(pyridyl) ligands with a chelating spacer: syntheses, structures and photoluminescence properties, Dalton Trans.,2015,44, 5837-5847.

2.      Ya-Nan Li, Li-Hua Huo, Zhao-Peng Deng,* Xin-Yu Xie, Zhi-Biao Zhu and Shan Gao*, Nature of reactant and influence of water on the supramolecular patterns and luminescent properties of organic salts comprising (1, 1’ -biphenyl)- 4, 4’ -disulfonate and triphenylmethanaminium, RSC Adv.,2015,5, 41692-41706.

3.      Yi-Zhe Yu, Ya-Nan Li, Zhao-Peng Deng,* Zhi-Biao Zhu, Li-Hua Huo, and Shan Gao*, Influence of Metal Cations and Coordination Modes on Luminescent Group 1 and 2 Metal Sulfonate Complexes Constructed from 4,4-Dihydroxybiphenyl- 3,3-disulfonic Acid, Eur. J. Inorg. Chem.,2015, 2254-2263.

4.      Ya-Nan Li, Li-Hua Huo, Zhao-Peng Deng,* Xin Zou, Zhi-Biao Zhu, Hui Zhao, and Shan Gao*, Solvent Effect on the Supramolecular Patterns and Luminescent Properties of Organic Salts Comprising Naphthalene-1,5-disulfonic Acid and Triphenylmethylamine, Cryst. Growth Des.,2014, 14, 23812393.

5.      Zhu-Yan Zhang, Zhao-Peng Deng, Xian-Fa Zhang, Li-Hua Huo,* Hui Zhao and Shan Gao*, Self-assembly of [Cu3I2]- or [CuI]n-based (n = 2, 4, and ) coordination polymers from unsymmetrical bis(pyridyl) and in situ ligands: syntheses, structures, and properties, CrystEngComm,2014, 16, 359-368.

6.      Tong-Peng Liu, Li-Hua Huo, Zhao-Peng Deng,* Hui Zhao and Shan Gao*, Supramolecular architectures and luminescent properties of the salts containing flexible bis(pyridyl) cations with aliphatic diamine spacer: effects of inorganic anions, alkalinity and conformation of the bis(pyridyl) cations, RSC Adv.,2014, 4, 40693-40710.

7.      Ya-Nan Li, Li-Hua Huo, Yi-Zhe Yu, Fa-Yuan Ge, Zhao-Peng Deng,* Zhi-Biao Zhu and Shan Gao*, Influence of solvents and assembly methods on the supramolecular patterns and luminescent properties of organic salts comprising 4,4- dihydroxybiphenyl-3,3-disulfonate and triphenylmethanaminium RSC Adv.,2014, 4, 64802-64815.

8.      Zhu-Yan Zhang, Zhao-Peng Deng, Li-Hua Huo,* Hui Zhao and Shan Gao*, Well-Designed Strategy To Construct Helical Silver(I) Coordination Polymers from Flexible Unsymmetrical Bis(pyridyl) Ligands:Syntheses, Structures, and Properties, Inorg. Chem.,2013, 52, 5914-5923.

9.      Zhu-Yan Zhang, Zhao-Peng Deng, Li-Hua Huo,* Hui Zhao and Shan Gao*, Inorganic anion induced supramolecular architectures of flexible unsymmetrical bis(pyridyl) ionic salts mediated by various non-covalent interactions, CrystEngComm,2013, 15, 5261-5274.

10.  Zhao-Peng Deng, Li-Hua Huo*,Hui Zhao, Shan Gao*, A strategy to tune the supramolecular patterns and luminescent properties: ten well-designed cocrystals assembled by arenedisulfonic acid with diverse diamines, Cryst. Growth Des.,2012, 12, 3342-3355.

11.  Zhao-Peng Deng, Wei Kang, Zhi-Biao Zhu, Li-Hua Huo*,Hui Zhao, Shan Gao*,Cation radii induced structural variation in fluorescent alkaline earth networks constructed from tautomers of a nucleobase analogue, Dalton Trans.,2012,41, 8354-8360.

12.  Zhao-Peng Deng, Zhu-Yan Zhang, Li-Hua Huo*, Seik-Weng Ng, Hui Zhao, Shan Gao*, Syntheses, crystal structures and properties of transition metal coordination polymers based on isophthalic acid and flexible bis(pyridyl) ligand with unsymmetrical spacer: influence of metal cations, ligand conformations and coordination modes,CrystEngComm,2012, 14, 6548-6558.

13.  Wang Wan, Zhi-Biao Zhu, Li-Hua Huo, Zhao-Peng Deng*, Hui Zhao, Shan Gao*, Syntheses, structures and luminescent properties of lithium(I)-sulfonate complexes constructed from ortho-hydroxyl arenedisulfonic acids: structural evolution tuned by the pH, coordination geometry and modes, CrystEngComm, 2012, 14, 5274-5284.

14.  Huang Wang,Li-Hua Huo, Zhao-Peng Deng*,Hui Zhao, Shan Gao*,Syntheses, crystal structures and luminescent properties of Zn(II)/Cd(II) supramolecular complexes incorporating 4-sulfinobenzoate and its in situ oxidized ligand,CrystEngComm, 2012,14, 3501-3508.

15.  Zhi-Biao Zhu, Wang Wan,Zhao-Peng Deng, Zhong-Yi Ge, Li-Hua Huo*, Hui Zhao, Shan Gao*, Structure modulations in luminescent alkaline earth metal-sulfonate complexes constructed from dihydroxyl-1,5-benzenedisulfonic acid: Influences of metal cations, coordination modes and pH value, CrystEngComm, 2012, 14, 6675-6688.

16.  Xian-Fa Zhang, Zhao-Peng Deng, Li-Hua Huo*, Qing-Mao Feng, Shan Gao*, Four alkali-Induced 3D strontium(II) coordination polymers constructed from imidazole-4,5-dicarboxylate: syntheses, crystal structures, and properties, Eur. J. Inorg. Chem.,2012, 5506-5514.

17.  Zhao-Peng Deng, Li-Hua Huo, Ming-Shuai Li, Li-Wei Zhang, Zhi-Biao Zhu*, Hui Zhao, Shan Gao*, Syntheses, Structures, and Luminescent Properties of Silver(I) Complexes Constructed from ortho-Hydroxyl Arenesulfonic Acids, Cryst. Growth Des., 2011, 11, 3090-3100.

18.  Xiang-Qian Fang, Zhao-Peng Deng, Li-Hua Huo*, Wang Wan, Zhi-Biao Zhu, Hui Zhao, Shan Gao*, New Family of Silver(I) Complexes Based on Hydroxyl and Carboxyl Groups Decorated Arenesulfonic Acid: Syntheses, Structures, and Luminescent Properties, Inorg. Chem.,2011, 50, 12562-12574.

19.  Zhao-Peng Deng, Ming-Shuai Li, Zhi-Biao Zhu, Li-Hua Huo*, Hui Zhao, Shan Gao*, Rare Organosilver(I) Coordination Polymers Constructed from Hydroxyl-Substituted Benzenesulfonic Acids: Syntheses, Structures and Characterizations, Organometallics,2011, 30, 1961-1967.

20.  Zhao-Peng Deng, Zhi-Biao Zhu, Xian-Fa Zhang, Li-Hua Huo*, Hui Zhao, Shan Gao*, The first in situ organosulfonate-templated 3-fold interpenetrating framework built from rare tetrahedral [Cu4(μ4-SO4)] SBUs, CrystEngComm, 2011,13, 3895-3899.

21.  Zhao-Peng Deng, Li-Hua Huo*, Hui Xu, Hui Zhao, Shan Gao*, The first metal–organic framework containing an unprecedented in situ-generated C-substituted hexamethylenetetramine ligand, Dalton Trans., 2011, 40, 1224-1226.

22.  Zhao-Peng Deng, Hui-Ling Qi, Li-Hua Huo*, Hui Zhao, Shan Gao*, Inorganic anion induced supramolecular architectures and luminescent properties of flexible bis(pyridyl) based ionic salts, CrystEngComm, 2011,13, 6632-6642. (Cover)

23.  Zhao-Peng Deng, Li-Hua Huo, Hui-Ling Qi, Li-Na Zhu, Hui Zhao, Shan Gao*, Structural diversity of Zn(II)/Cd(II) complexes based on bis(pyridyl) ligands with a long flexible spacer: From zero-dimensional binuclear, one-dimensional chain, two-dimensional layer, to three-dimensional frameworks, CrystEngComm, 2011,13, 4218-4227.

24.  Zhao-Peng Deng, Li-Hua Huo, Huan-Yu Wang, Shan Gao*, Hui Zhao, A series of three-dimensional lanthanide metal–organic frameworks with biphenylethene- 4, 4 -dicarboxylic acid: Hydrothermal syntheses and structures, CrystEngComm,2010, 12, 1526-1535.

25.  Zhao-Peng Deng, Wei Kang, Li-Hua Huo, Hui Zhao, Shan Gao*, Rare-earth organic frameworksinvolving three types of architecture tuned by the lanthanide contraction effect: hydrothermal syntheses, structures and luminescence, DaltonTrans., 2010,39, 6276-6284.

26.  Zhao-Peng Deng,Hui-Ling Qi,Li-Hua Huo,*Seik Weng Ng,Hui Zhaoand Shan Gao*, Syntheses and structures of copper(I) complexes based on CunXn (X = Br and I; n = 1, 2 and 4) units and bis(pyridyl) ligands with longer flexible spacer, DaltonTrans., 2010,39, 10038-10050.

27.  Zhao-Peng Deng,Zhi-Biao Zhu,Shan Gao*,Li-Hua Huo,Hui Zhao, Seik Weng Ng, A series of silver(I) pyridone-sulfonates with 1-D “butterfly” chain, 2-D lamellar network and 3-D pillared layered frameworks: syntheses, structures and characterizations, Dalton Trans., 2009, 6552-6561.

28.  Zhao-Peng Deng, Zhi-Biao Zhu, Shan Gao*, Li-Hua Huo, Hui Zhao, The first continuous silver polyhedra framework containing four kinds of coordination spheres, Dalton Trans., 2009, 1290-1292.

29.  M. Yang, L. H. Huo, H. Zhao, S. Gao, Z. M. RongElectrical properties and acetone-sensing characteristics of LaNi1-xTixO3 perovskite system prepared by amorphous citrate decompositionSensors and Actuators B, 2009, 143, 111-118 SCI, 3.37

30.  Zhao-Peng Deng, Li-Na Zhu, Shan Gao*, Li-Hua Huo, Seik Weng Ng, Self-Assembly of Discrete Metallocycle versus Coordination Polymer Based on Silver(I) and Di-2- and Di-3-pyridines with Flexible Spacer, Crystal Growth Des.,2008, 8, 3277-3284.

31.  H. Y. Wang, S. Gao, L. H. Huo, S. W. Ng, and J. G. Zhao, Three Interpenetrated Frameworks Assembly from a Long Multicarboxylate Ligand and Transition Metal, Cryst. Growth Des., 2008, 8, 665-670 (SCI, 4.39)

32.  S. Pokhrel, L. H. Huo, H. Zhao, S. Gao, Triangular network of crystalline submicron rutile TiO2 block assembly: An alcohol sensorSensors and Actuators B, 2008, 12918-23SCI, 3.37

授权专利:

1.      霍丽华,苏曼,赵辉,高山,程晓丽. 敏感材料及用敏感材料制成的甲醛敏感元件及敏感元件的制作方法,ZL200710071884.X2010

2.      霍丽华,杨铭,赵辉,高山,程晓丽.一种丙酮气敏材料及其应用.ZL200710144666.42010

3.      程晓丽,霍丽华,徐英明,高山,赵辉,由三种维度单元构建的多级结构氧化锌及其制备方法,ZL201010120106.72011

4.      徐英明,霍丽华,马骅,程晓丽,高山,赵辉,类立方体纳米单元构筑的尺寸可控的单分散氧化铬多孔微球及其制备方法,2013.12, 中国发明专利, ZL201210096028.0

5.      程晓丽;霍丽华; 宋肖肖; 徐英明; 张现发; 高山; 赵辉,多级结构花状二氧化钼的制备方法,2014.,7,中国发明专利,ZL201210417187.6

6.      程晓丽;霍丽华; 宋肖肖; 徐英明; 张现发; 高山; 赵辉,一种二氧化钼核壳微球的制备方法,2014.,7,中国发明专利,ZL201210417156.0

主要获奖:

1.      霍丽华,高山,赵辉,徐英明,程晓丽,氧化物基纳米材料的组装与气敏性质研究,黑龙江省高校科学技术奖一等奖,2011.03

2.      赵辉,霍丽华,高山,李强,孙丽萍. 纳米氧化物材料的软化学合成及性质研究. 黑龙江省科学技术二等奖,2008.06

3.      霍丽华,高山,赵经贵,蔡庄,程晓丽. 纳米氧化物及其杂化薄膜的组装与性能研究. 黑龙江省科学技术二等奖,2003.08

主要在研项目:

1.      黑龙江省自然科学基金面上项目,B2015007,《基于芳香磺酸建构的荧光超分子晶态网络材料的设计与调控》,2015.07-2018.07,主持。

2.      国家自然科学基金,51302067,《光功能芳香磺酸晶态网络材料的设计与合成》,2014.01-2016.12,第二。

     代表性结题项目:

1.      黑龙江省自然科学基金重点项目,ZD200903,新型纳米多孔配位聚合物材料的组装与性能研究》,2010.01-2012.12,主持。

2.      黑龙江省教育厅科学技术研究重点项目,12511Z023,具有纳米孔金属有机分子筛材料的构筑与性能研究2011.01-2013.12,主持。

 

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